A set of classical equations relating the vector quantities applying at any point in a varying electric or magnetic field. The four basic equations are:
H is the magnetic field strength, D the electric displacement, t is time, j is the current density, B the magnetic flux density, E the electric field strength, and ρ the volume charge density.
From these equations Maxwell deduced that each field vector obeys a wave equation; he also showed that in free space, where j = 0 and ρ = 0, the solutions represent a transverse wave travelling through space with the speed of light, c. These waves are known as electromagnetic waves (see electromagnetic radiation). Further work showed that certain properties of these waves, i.e. reflection, refraction, and diffraction, are identical to the properties of light waves and that light waves are a form of electromagnetic radiation.
Maxwell’s theory deals only with macroscopic phenomena and does not offer an explanation of phenomena arising from interactions on an atomic scale, such as dispersion and the photoelectric effect. On an atomic scale it has been found necessary to introduce the quantum mechanical theory of electromagnetic radiation.
From Maxwell’s equations it is possible to deduce the wave velocity in a medium as
where ε is the permittivity of the medium and μ is its permeability, μ = B/H. In a vacuum the wave velocity is given by
Thus in a nondispersive medium of refractive index n, where n = c/v,
or in a nonferromagnetic material where μr ≊ 1,
where εr is the relative permittivity of the medium and μr the relative permeability. This is known as Maxwell’s formula. In a dispersive medium the above formula applies provided that all measurements are carried out at the same frequency.