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角锥交叉
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角锥交叉
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conical intersection
角锥交叉
在多原子分子中,两个具有相同对称性与自旋的电子态,其势能曲面在某个几何结构下能量简并,且非绝热耦合效应并不消失的现象。在此处两个电子态的势能面形成圆锥面,又称锥形交叉。
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