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氮氧自由基调控聚合
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氮氧自由基调控聚合
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氮氧自由基调控聚合
释
nitroxide mediated polymerization
氮氧自由基调控聚合
利用氮氧自由基与自由基聚合过程中的增长自由基结合成休眠种,在特定温度下建立休眠种和活性自由基之间的快速动态平衡,从而降低活性自由基浓度,抑制增长自由基的不可逆链终止反应,实现对聚合物端基、分子量及其分布控制的聚合方法。是最早发展的可控自由基聚合反应。
Chemistry
>高分子科学>高分子化学>释义
nitroxide-mediated polymerization (NMP)
氮氧自由基调控聚合
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