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抓桥氢
释义
抓桥氢
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理学
“抓”桥氢
释
agostic hydrogen
抓桥氢
过渡金属配合物的σ-烷基或芳基配体中,能作为2电子给体与配位不饱和的中心金属原子的d空轨道配位成键,形成M—H—C(M表示过渡金属原子)三中心二电子的抓氢键的氢原子。
Chemistry
>有机化学>金属有机化学>释义
agostic hydrogen
“抓”桥氢
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