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微扰理论
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微扰理论
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流体统计热力学
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perturbation theory
微扰理论
将一个实际体系的表示分子间作用力的位能函数,看作是一个参考体系的位能函数与微扰项的加和,从而计算体系热力学性质的统计热力学理论。将系统的位能划分为参考态和微扰态,并在此基础上建立起流体的微扰理论。
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