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one-electron approximation
释义
one-electron approximation
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理学
计算与理论化学
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one-electron approximation
单电子近似
在多电子体系中,由于存在电子间的相互作用,所以无法严格地确定其中单个电子的状态。但是可以在一定的物理限制之下将多个单电子波函数通过人为组合近似描述整个体系的波函数的方法。又称独立电子模型或轨道近似。
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