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ligand cone angle
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ligand cone angle
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理学
配位体锥角
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ligand cone angle
配位体锥角
在配合物中,金属中心顶点和配体原子所占范德华球体积最外层边缘所形成的锥体立体角。它是配体空间体积的一种评估方法〔一个常见的例子是托尔曼(Tolman)锥角或θ〕。叔膦配体常用该参数进行分类,但该方法适用于任何配体。
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ligand cone angle
配位体锥角
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